While on the topic of configuring labwc, for the desktop to feel polished it should probably have a background image and a taskbar.
For setting a background image there's swaybg.tcz. For taskbar, current options in the x86_64 repo are sfwbar.tcz and waybar.tcz.
In labwc, startup commands go in the ~/.config/labwc/autostart file. This file itself does not have to have executable permission (i.e., 644 permissions on this file are fine). File could look like this, for example:
swaybg -i /path/to/some/nice/image.jpg &
sfwbar &