shortcut to VLC mixer levels is CTRL + e keys
The master volume is still in bottom right corner of player.
click small icon to left of volume to mute
I use mouse to slide volumes to right of icon.
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the non working alasamixergui irks me so much.
Are you still having troubles with VLC or with alsamixergui?
Have you tried the terminal command
alsamixer -c1
If interested, we can offer ways of fixing alsamixergui to NOT need -c1
but it involves swapping your card index.
It might help if I know how well you have grasped the idea of persistence
especially in relation to starting up a media player and the volumes to play the last track
are exactly the same.
It can lead to information overload, so no need to reply for a few days.