Unfortunately PCM was still re-booting muted, so the commands listed below were moved from /opt/bootlocal.sh to /home/tc/.X.d/startups file. Persistent good volume upon several reboots. Makes more sense anyway as the commands don't require root.
amixer set Master unmute &
amixer set PCM unmute &
amixer set Master 80% &
amixer set PCM 80% &
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